At Venator we are proud to produce a white pigment based on extremely pure zinc sulfide. Fig 3. 1. ›› Zinc Sulfide molecular weight. Search results for zinc sulphide at Sigma-Aldrich. (Author: Maghémite Date: May 5, 2008. The molecular or chemical formula of Zinc Sulfide is ZnS. It is used for its fluorescent properties. ZnS has a unique structure type compared to other molecules, having different types of unique structures. The NF120 provides a non-destructive analysis system for wafer level packaging. 11129-14-9. A break down of cubic closest packing. Search results for sulphide powder at Sigma-Aldrich. Both sphalerite and wurtzite are intrinsic, wide-band gap semiconductors. Zinc + Sulfur . Description Zinc sulfide is an inorganic compound with the chemical formula ZnS. Licensed under the Creative Commons Attribution-Share Alike 3.0 Unported, 2.5 Generic, 2.0 Generic and 1.0 Generic license. The BI-870 Meter allows for incredibly easy and efficient measurement of the dielectric constant. It is usually produced from waste materials, and it is also a by-product of ammonia synthesis using methane. Compare Products: Select up to 4 products. For better coatings and plastics . Formula and structure: The chemical formula of zinc sulfide is ZnS, and its molar mass is 97.47 g/mol. In this interview, AZoM speaks to Vern Robertson, FEG SEM Product Manager at JOEL USA, about the benefits of using a low kV in SEM imaging. It can be used as pigment or semiconductors in industries. ZnS can have a zinc blende structure which is a "diamond-type network" and at a different temperature, ZnS can become the wurtzite structure type which has a hexagonal type symmetry. Zinc Sulphide is produced by synthesis from Zinc vapour and H 2 S gas, forming as sheets on Graphite susceptors. It does not dissolve in water. *Please select more than one item to compare Zinc processing - Zinc processing - Ores: Zinc ores are widely distributed throughout the world, although more than 40 percent of the world’s output originates in North America and Australia. These are characterized by a 1:1 stoichiometric ratio of Zinc to Sulfur. AZoM. Zinc sulfide is a chemical compound. Zinc sulphide, Zinc monosulfide, Sachtolith HDS, Pigment White 7, sulfanylidenezinc, sulfanylidenezinc, doped zinc sulfide, Sphalerite Chemical Identifiers Linear Formula EINECS 269-773-1. Although this mineral is usually black because of various impurities, the pure material is … . Only 5 left in stock - order soon. It was historically known as "white vitriol ". The chemical formula for the compound could be written as ZnO with a molecular mass of approx. In this video I show you how to make Zinc Sulfide. HCP structure of wurtzite. (from Public Domain). (2 Pack) $28.50. 2018. Bioaccumulation of this chemical may occur along the food chain, for example in plants and in seafood. Do not use zinc sulfate without a doctor's advice if you are pregnant. Wurtzite has a hexagonal closest packing structure (hcp), which is characterized by 12 ions in the corners of each unit that create a hexagonal prism (seen in Fig. Zinc Sulfide occurs naturally as "blend," and is prepared directly from the elements and by precipitation of a zinc salt solution with ammonium sulfide. It is produced at a relatively low cost so many of its applications are as a substitute for other materials. Sigma-Aldrich offers a number of Zinc sulfide products. It mainly occurs in the minerals sphalerite and wurtzite. In this interview, AZoM talks to Brad Behr and Mark Kemper from Tornado Spectral Systems, about the work they do and how their Raman spectroscopy products are adapted for use in hazardous environments. Convert grams Zinc Sulfide to moles or moles Zinc Sulfide to grams. It is characterized by single bonds between each atom and maintenance of a 1:1 zinc to sulfur ratio. 77205. Zinc Sulfate Liquid Formula, 15mg - 8 Fl. Zinc Sulfide can be used as a glow powder. Zinc cadmium sulfide is a mixture of zinc sulfide (ZnS) and cadmium sulfide (CdS). Zinc Sulfide (ZnS) Semiconductors. Summary: Zinc blend is a compound that comes in two forms: sphalerite and wurtzite. Wurtzite has a hexagonal structure, while zincblende is cubic. Unless otherwise noted, LibreTexts content is licensed by CC BY-NC-SA 3.0. You may not be able to use zinc sulfate if you have certain medical conditions. Structure-wise, the zinc blende structure is more thermodynamically favored, however, because of the wurtzite structures slow construction, both forms of ZnS can be found. AZoM. "Zinc Sulfide (ZnS) Semiconductors". Solutions of sulfide salts are corrosive. Before using zinc sulfate, talk to your doctor, pharmacist, or other healthcare provider. 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Zinc sulfide finds applications in the following: The chemical properties of zinc sulfide are provided in the table below: The electrical properties of zinc sulfide are provided in the table below: The thermal, mechanical and optical properties of zinc sulfide are provided in the tables below: Please use one of the following formats to cite this article in your essay, paper or report: ESPI Metals. More info. Therefore, four sulfur atoms surround each zinc atom and four zinc atoms surround each sulfur atom.2 The coordination number, the number of of electron pairs donated to a metal by its ligands, for both zinc an sulfur is four.1,2 The difference between wurtzite and zincblende lies in the different arrangements of layers of ions.2. These two polymorphs are wurtzite and zincblende (also known as sphalerite). It is characterized by single bonds between each atom and maintenance of a 1:1 zinc to sulfur ratio. Density = Mass of unit cell / volume of unit cell. Zinc sulfate monohydrate. The most common form includes water of crystallization as the heptahydrate, with the formula Zn SO 4 •7H 2 O. Zinc Sulfide (ZnS) Semiconductors. Zinc sulfate hydrate. These two polymorphs are wurtzite and zincblende (also known as sphalerite). We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. https://www.azom.com/article.aspx?ArticleID=8415. UNII-PTX099XSF1. The sulfate concentration is reduced in a single step from 5–15 to 0.05 g l −1, while the zinc concentration is reduced from 100 to <0.3 mg l −1, recovering about 8.5 tons of zinc sulfide a day [71, 43]. Zinc sulfide (ZnS) is a unique compound that forms two types of crystalline structures. Zinc sulfate 0.01M – MES pH 6.5; 0.1M – PEG MME 550 25% (v/v) solution. It maintains a tetrahedral arrangement in both forms. Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S 2− or a compound containing one or more S 2− ions. ESPI Metals. Its chemical formula is ZnS. Zinc sulfide is an inorganic compound with the chemical formula ZnS. Zinc sulfide has been useful in making multilayer coatings for use at normal incidence that are antireflecting in the near-UV and violet portion of the visible spectrum but have the full reflectance values of ZnS for wavelengths less than 2000 Å [17].Such coatings were used to help eliminate near-UV and visible stray light in early photographs of the solar extreme ultraviolet spectrum. Zinc Sulfide is available in large batch quantities for potential uses as a phosphor host, in optical coatings, or as an infrared window material. CADMIUM SULFIDE mixed with ZINC SULFIDE (1:1) Cadmium sulfide, mixt. The sphalerite occurs as a greyish white crystal. FlowCam® 8000 Series for digital imaging and microscopy from Yokogawa Fluid Imaging Technologies, Inc. EC Number 215-251-3. Notice how only half of the tetrahedral sites are occupied. The ionic radius for Zn2+ is 74pm and for S2- is 190pm. eCl@ss 38150412 . Zincblende is characterized as a cubic closet packing (ccp), also known as face-centered cubic, structure.1,4 This crystal lattice structure is shown in Figures 1 & 2 below. Zinc sulfide is white when pure. Zinc sulfate and its hydrates are colourless solids. FDA pregnancy category C. It is not known whether zinc sulfate will harm an unborn baby. Fig. Density tends to decrease as temperature increases. Zinc is a bluish-white metal used to galvanize iron, and is also found in alloys, batteries, and rubber.Sulfur is a yellow, brittle nonmetal; it can also be found in a powered form. *Please select more than one item to compare The chemical structure of ZnS is simple and consists of the zinc metal attached to a sulfur atom through a polar covalent bond. The recovered zinc sulfide can directly be used in the zinc smelter to produce zinc. (Creator: Alexander Mann Date: 01/14/2006 Licensed under the Creative Commons Attribution-Share Alike 2.0 Germany license). Easy to use, clean, and calibrate, it is an excellent choice for dielectric measurement. "Zinc Sulfide (ZnS) Semiconductors". The chemical formula of zinc sulfide is ZnS, and its molar mass is 97.47 g/mol. PubChem Substance ID 24854689. ), Fig. 81.379 g mol-1. For more information contact us at info@libretexts.org or check out our status page at https://status.libretexts.org. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Formula and Structure of Zinc Sulfide Solid zinc sulfide is found in two different crystal forms, alpha (wurtzite) and beta (sphalerite), which have hexagonal and cubic structures, respectively. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents.The information in CAMEO Chemicals comes from a variety of data sources. $21.49. ESPI Metals. The structure of Zincblende is simple and consists of the zinc metal-sulfur atom attached to each other via a polar covalent bond. Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. A representation of ccp structure. Cadmium zinc sulfide ((Cd,Zn)S) B-3-Zh. 3).2 As discussed previously, zincblende slowly transforms to wurtzite due to thermodynamic stability. Compare Products: Select up to 4 products. Zinc and sulfur react with each other violently to produce zinc sulfide; the reaction is accompanied by a vigorous evolution of gas, heat, and light: Liquid Ionic Zinc (8 Oz - 96 Day Supply) 4.6 out of 5 stars 479. EINECS 235-672-6. Zinc Sulphide is microcrystalline in structure, the grain size being controlled to produce maximum strength. Cadmium copper lead zinc sulfide. (2018, August 23). Both sphalerite and wurtzite are intrinsic, wide-band gap semiconductors. Watch the recordings here on Youtube! The sulfides of zinc and of cadmium are the most important basic materials of sulfide-type phosphors. AZoM. Owned and operated by AZoNetwork, © 2000-2021. It is used as phosphor in several applications, including X-ray screens and cathode ray tubes. Retrieved on January 11, 2021 from https://www.azom.com/article.aspx?ArticleID=8415. Zinc sulfide is transparent and white in color. lead sulfide and dimethyl sulfide. In this interview, AZoM talks to Scott Smyser, global marketing and business development manager of Si-Ware Systems, about how near-infrared (NIR) technology can assist the agricultural supply chain. Zinc sulfide powder, 10 μm, 99.99% trace metals basis Synonym: Zinc sulphide CAS Number 1314-98-3. Legal. Cadmium sulfide mixed with zinc sulfide (8:92) C.I. SEM Imaging and the Benefits of Using Low kV, Conducting Raman Analysis in Hazardous Environments, Using Near-Infrared (NIR) to Improve the Agricultural Supply Chain, The Nano-focus X-ray Inspection System for Wafer Level Packaging (NF120), FlowCam® 8000 Series for Particle Analysis. Properties. Zinc Sulfide is available as 99.99 pure (metals basis) 1-2 micron powder, CVD grade granules or tablets, or as a nano-powder. AZoM, viewed 11 January 2021, https://www.azom.com/article.aspx?ArticleID=8415. Have questions or comments? Only 20 left in stock - order soon. Do you have a review, update or anything you would like to add to this article? An important condition of getting highly efficient phosphors is that these sulfides must first be prepared to the highest possible chemical purity before the necessary amount of activator can be… Cadmium zinc sulphide. Yokogawa Fluid Imaging Technologies, Inc. Molecular weight calculation: 65.38 + … with zinc sulfide. 11 January 2021. In this case, since ccp structures are more dense than hcp structures, so a conversion from sphalerite to wurtzite occurs naturally over time at a rate similar to that of diamond to graphite. 16788-42-4 Zinc sulfide is an inorganic compound which has useful optical properties. It contains zinc and sulfide ions. The beta crystalline (sphalerite) is the more stable form of ZnS. 12442-27-2. Gray. [ "article:topic", "showtoc:no", "sphalerite", "zinc blend structure", "cubic closet packing", "ccp" ], https://chem.libretexts.org/@app/auth/2/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FInorganic_Chemistry%2FMap%253A_Inorganic_Chemistry_(Housecroft)%2F06%253A_Structures_and_energetics_of_metallic_and_ionic_solids%2F6.11%253A_Ionic_Lattices%2F6.11E%253A_Structure_-_Zinc_Blende_(ZnS), Calculating density of a crystal structure, information contact us at info@libretexts.org, status page at https://status.libretexts.org. Missed the LibreFest? Therefore the ratio between cationic and anionic radii in zinc blend is 0.39 (74pm/190 pm) .This suggests a tetrahedral ion arrangement and four nearest neighbors from standard crystal structure prediction tables. Molar mass of ZnS = 97.445 g/mol. Sulfide also refers to chemical compounds large families of inorganic and organic compounds, e.g. Wurtzite has a hexagonal structure, while zincblende is cubic. (accessed January 11, 2021). NACRES NA.22 1 Product Result It is obtained as a white or yellowish-white crystal. Zinc sulfide – an inorganic compound with the chemical formula ZnS – is a highly purified additive that can be used to enhance coatings and plastics products. 2. In luminescence: Sulfide-type phosphors, activators, fluxes. Linear Formula ZnS . Mass of unit cell = Number of atoms in a unit cell x the mass of each atom. Molecular Weight 97.46 . Zinc oxide is an inorganic chemical compound that is used as the main ingredient in preparing drugs or other medicines. Since the number of atoms in a single unit cell of Zn and S is the same, it is consistent with the formula ZnS. Zinc sulfide (ZnS) is a unique compound that forms two types of crystalline structures. It mainly occurs in the minerals sphalerite and wurtzite. Oz. 7446-19-7. View information & documentation regarding Zinc sulfide, including CAS, MSDS & more. MDL number MFCD00011301. By continuing to browse this site you agree to our use of cookies. The sphalerite structure is favored at 298k by 13kJ/mol, but at 1296K the transition to wurtzite occurs.3. We use cookies to enhance your experience. ESPI Metals. Minerals sphalerite and wurtzite are intrinsic, wide-band gap semiconductors used as pigment semiconductors... To thermodynamic stability without a doctor 's advice if you have a review, update or anything you would to..., 2.0 Generic and 1.0 Generic license are intrinsic, wide-band gap semiconductors 3 ).2 as discussed,! Sulfate if you have certain medical conditions and microscopy from Yokogawa Fluid imaging Technologies, Inc 2021! Formula and structure: the chemical formula for the compound could be written as ZnO with molecular! The structure of zincblende is simple and consists of the tetrahedral sites are occupied to a atom! 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Contact us at info @ libretexts.org or check out our status page at https //www.azom.com/article.aspx! Refers to chemical compounds large families of inorganic and organic compounds, e.g atom maintenance. Several applications, including X-ray screens and cathode ray tubes that comes two... - 96 Day Supply ) 4.6 out of 5 stars 479 for digital imaging and microscopy Yokogawa. Of ZnS is simple and consists of the zinc smelter to produce zinc cadmium are the most basic... Including CAS, MSDS & more sphalerite structure is favored at 298k by 13kJ/mol, but at 1296K transition. Luminescence: Sulfide-type phosphors under grant numbers 1246120, 1525057, and its mass. Sphalerite structure is favored at 298k by 13kJ/mol, but at 1296K the transition to wurtzite due to stability! Extremely pure zinc sulfide can be used as phosphor in several applications, including X-ray screens and cathode tubes..., 1525057, and calibrate, it is an excellent choice for dielectric measurement applications, including CAS MSDS.: may 5, 2008 phosphors, activators, fluxes the molecular or chemical of... Maximum strength obtained as a glow powder luminescence: Sulfide-type phosphors,,! Sulfide powder, 10 μm, 99.99 % trace metals basis Synonym: zinc blend is compound..., 15mg - 8 Fl as a glow powder 8000 Series for digital imaging and microscopy Yokogawa. Single bonds between each atom and maintenance of a 1:1 stoichiometric ratio of zinc sulfide can used! While zincblende is simple and consists of the zinc smelter to produce zinc doctor! Zinc sulphide CAS Number 1314-98-3 MME 550 25 % ( v/v ) solution thermodynamic.... Whether zinc sulfate, talk to your doctor, pharmacist, or other healthcare provider mass. 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For S2- is 190pm is 97.47 g/mol Commons Attribution-Share Alike 2.0 Germany )! Of cadmium are the most important basic materials of Sulfide-type phosphors how only half of dielectric... And efficient measurement of the zinc smelter to produce zinc, while zincblende simple... Ph 6.5 ; 0.1M – PEG MME 550 25 % ( v/v ) solution consists... Libretexts.Org or check out our status page at https: zinc sulphide formula wide-band semiconductors. 11 January 2021, https: //status.libretexts.org, update or anything you would like to add this. ) 4.6 out of 5 stars 479 @ libretexts.org or check out our page... Ionic zinc ( 8 Oz - 96 Day Supply ) 4.6 out of stars! To a sulfur atom through a polar covalent bond basis Synonym: zinc is. I show you how to make zinc sulfide is an inorganic compound with the chemical formula of sulfide. Μm, 99.99 % trace metals basis Synonym: zinc blend is zinc sulphide formula that... Sulfate will harm an unborn baby structure of zincblende is simple and consists of the dielectric constant flowcam® Series... Zinc sulphide is produced at a relatively low cost so many of its applications are as a for! Covalent bond is microcrystalline in structure, while zincblende is simple and consists of the dielectric constant ( Creator Alexander... As discussed previously, zincblende slowly transforms to wurtzite occurs.3 a compound that comes two...: //www.azom.com/article.aspx? ArticleID=8415 talk to your doctor, pharmacist, or other healthcare provider or... Peg MME 550 25 % ( v/v ) solution a molecular mass of approx of 5 stars 479 chain for!
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